WASSCE Physics · States of Matter and Kinetic Theory

States of matter and the kinetic theory

By the WASSCE Tutor team

Updated 10 November 2026 · 7 min read · Prepared against the WASSCE syllabus.

Why does the smell of fried fish reach the next room? Why does a wet cloth dry in the sun? Why does ice melt but a stone does not? All of these are explained by one idea: everything is made of tiny particles that never stop moving.

Learning objectives

By the end of this lesson you should be able to:

  • state the main points of the kinetic theory of matter
  • describe the arrangement and motion of particles in solids, liquids and gases
  • explain Brownian motion and diffusion as evidence for moving particles
  • use the kinetic theory to explain the properties of the three states

The kinetic theory of matter

Definition

The kinetic theory of matter states that:

  1. all matter is made up of tiny particles (atoms, molecules or ions)
  2. these particles are in constant, random motion
  3. there are forces of attraction between the particles, which are strongest when they are close together
  4. the higher the temperature, the faster the particles move (the greater their average kinetic energy)

The three states of matter

Three boxes of particles: in a solid they are tightly packed in a regular pattern; in a liquid they are close but irregular; in a gas they are far apart moving quickly in random directions

Figure 1. Particles in a solid, a liquid and a gas. WASSCE Tutor diagram.

PropertySolidLiquidGas
Arrangementclosely packed, regular patternclose together, irregularfar apart, random
Motionvibrate about fixed positionsmove past one anothermove rapidly in all directions
Forces between particlesvery strongstrong, but weaker than in solidsvery weak (almost none)
Shapefixedtakes the shape of the containerfills the whole container
Volumefixedfixednot fixed
Compressibilityalmost incompressiblealmost incompressibleeasily compressed
Densityhighhighlow

Explaining the properties

  • Solids keep their shape because strong forces hold each particle in place; the particles can only vibrate.
  • Liquids flow because the particles, though close, can slide past one another.
  • Gases fill their containers and are easily squashed because the particles are far apart with large empty spaces between them.

Evidence for moving particles

Brownian motion

Definition

Brownian motion is the continuous, random, zig-zag movement of small particles (such as smoke or pollen grains) suspended in a fluid.

Smoke-cell experiment. A little smoke is trapped in a small glass cell, lit from the side and viewed through a microscope. The smoke particles appear as bright specks that move jerkily and randomly.

Explanation: the smoke particles are being bombarded unevenly by the invisible air molecules, which are moving rapidly and randomly. At any moment more molecules hit one side than the other, so the particle is pushed first one way, then another. Raising the temperature makes the motion more vigorous.

Common mistake

In the smoke cell you do not see air molecules — they are far too small. You see the smoke particles, which are moved about by the air molecules hitting them.

Diffusion

Definition

Diffusion is the spreading of particles from a region of higher concentration to a region of lower concentration until they are evenly mixed, as a result of their random motion.

  • The smell of perfume or of food cooking spreads through a room.
  • A crystal of potassium permanganate placed in water slowly colours all the water purple, without stirring.
  • Bromine vapour spreads through a gas jar of air.

Diffusion is fastest in gases (particles far apart and fast), slower in liquids, and extremely slow in solids. It is faster at higher temperatures and for lighter molecules.

In Sierra Leone

When a neighbour fries fish with pepper in the compound, you can smell it inside your house within seconds. The smell molecules diffuse through the air. On a hot afternoon the smell travels faster than on a cool morning.

Changes of state, explained

ChangeWhat happens to the particles
Melting (solid → liquid)heat makes particles vibrate so strongly that they break free of fixed positions
Boiling / evaporation (liquid → gas)the most energetic particles escape the attractive forces completely
Condensation (gas → liquid)cooled particles slow down and are pulled together by attractive forces
Freezing (liquid → solid)particles lose energy and settle into fixed positions

During melting and boiling the energy supplied breaks the bonds between particles instead of raising the temperature. This is the latent heat, studied later.

Gas pressure and temperature

Gas particles constantly collide with the walls of their container. Each collision exerts a tiny force; together they produce the pressure of the gas. Heating the gas makes the particles move faster, so they hit the walls more often and harder: the pressure rises. This is why a car tyre's pressure is higher after a long drive and why aerosol cans warn "do not heat".

Key points

  • Matter is made of tiny particles in constant random motion with attractive forces between them.
  • Solid: fixed positions, vibrating. Liquid: close but mobile. Gas: far apart, fast, random.
  • Brownian motion (smoke cell) and diffusion are evidence that particles move.
  • Higher temperature → faster particles → faster diffusion, more gas pressure.

WASSCE examination focus

WAEC tests this

Expect to state the assumptions of the kinetic theory, describe and explain the smoke-cell (Brownian motion) experiment, explain diffusion with an example, and use the kinetic theory to explain why gases are compressible, why liquids flow, or why gas pressure rises with temperature. Always refer to particles and their motion in your explanation.

Quick check

  1. In Brownian motion, what causes the random movement of smoke particles?
  2. Why is a gas easily compressed but a liquid is not?
  3. Give one everyday example of diffusion.

Answers: 1. Uneven bombardment by fast-moving, invisible air molecules. 2. Gas particles are far apart with large spaces between them; liquid particles are already close together. 3. For example: the smell of cooking spreading through a house.

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