WASSCE Chemistry · Solutions and Solubility

Solutions, suspensions and colloids

By the WASSCE Tutor team

Updated 12 November 2026 · 8 min read · Prepared against the WASSCE syllabus.

Stir salt into water and it vanishes; stir in mud and it clouds the water, then slowly settles; stir in powdered milk and the mixture stays cloudy but never settles. These are the three kinds of mixture of a substance in a liquid: solutions, suspensions and colloids. This lesson explains how they differ and why colloids matter from cooking to water treatment.

Learning objectives

By the end of this lesson you should be able to:

  • define solution, solute and solvent, and name common solvents and their uses
  • distinguish saturated, unsaturated and supersaturated solutions
  • distinguish true solutions, suspensions and colloids by their properties
  • describe the Tyndall effect
  • name the types of colloids, with examples, and describe coagulation

Solutions

Definition
  • A solution is a uniform (homogeneous) mixture of two or more substances.
  • The solute is the substance that dissolves; the solvent is the substance it dissolves in.
  • A solution in water is an aqueous solution.

Salt solution: salt is the solute, water the solvent. Solutions are not only solids in liquids. Air is a solution of gases, soda water a gas in a liquid, and brass a solid solution of zinc in copper.

Solvents and their uses

SolventDissolvesEveryday use
WaterSalts, sugars, many acids and basesCooking, cleaning, medicines
EthanolIodine, resins, perfume oils, some dyesTincture of iodine, perfumes, medicines
Propanone (acetone)Nail varnish, grease, plasticsNail-varnish remover
Kerosene / turpentineOil paint, grease, tarThinning paint, removing grease and tar
Trichloroethane / tetrachloroetheneGreaseDry cleaning

"Like dissolves like": ionic and polar substances dissolve in polar solvents such as water; non-polar substances (oils, fats, grease) dissolve in non-polar solvents such as kerosene.

Saturated, unsaturated and supersaturated solutions

Definition
  • An unsaturated solution can dissolve more solute at that temperature.
  • A saturated solution contains the maximum amount of solute that can dissolve at that temperature, with undissolved solute present.
  • A supersaturated solution contains more solute than a saturated solution at that temperature. It is unstable: adding a tiny crystal (seeding) makes the excess crystallise out at once.

Testing for saturation: add a little more solute at the same temperature. If it does not dissolve, the solution is saturated.

Making a supersaturated solution: prepare a saturated solution of sodium thiosulphate (or sodium ethanoate) while hot, then let it cool undisturbed.

Solutions, suspensions and colloids

PropertyTrue solutionColloidSuspension
Particle sizeVery small (below about 1 nm): ions and moleculesIntermediate (about 1–1000 nm)Large (above about 1000 nm)
AppearanceClear and transparentUsually cloudy or translucentCloudy, opaque
Settles on standing?NoNoYes
Passes through filter paper?YesYesNo: residue left
Tyndall effectNo: beam invisibleYes: beam visibleParticles may be seen
ExamplesSalt solution, sugar solutionMilk, starch solution, fog, blood, gelatinMuddy water, chalk in water, sand in water

The Tyndall effect

A light beam passes invisibly through salt solution but is clearly visible through starch solution, because colloid particles scatter the light

Figure 1. The Tyndall effect distinguishes a colloid from a true solution. WASSCE Tutor diagram.

Definition

The Tyndall effect is the scattering of light by colloid particles, which makes the path of a light beam visible in a colloid but not in a true solution.

You see the Tyndall effect when sunlight streams through dusty air in a room or through mist in the morning, and when car headlights shine through fog.

Types of colloids

A colloid has a dispersed phase (the particles) spread through a dispersion medium.

TypeDispersed phase in mediumExamples
SolSolid in liquidStarch solution, paint, ink, blood
GelLiquid in solidJelly, gelatin, hair gel
EmulsionLiquid in liquidMilk, mayonnaise, palm-oil sauces, cream
FoamGas in liquidShaving foam, whipped cream, soap lather
Solid foamGas in solidFoam rubber, bread, pumice
AerosolLiquid or solid in gasFog, mist, clouds (liquid); smoke, dust (solid)

An emulsifying agent keeps an emulsion from separating. Soap emulsifies grease in water; egg yolk emulsifies oil in mayonnaise.

Coagulation of colloids

Colloid particles often carry the same electric charge, so they repel each other and stay dispersed. Adding ions of opposite charge cancels this and makes the particles clump and settle: this is coagulation.

  • Alum (Al³⁺ ions) coagulates clay particles in water treatment.
  • Blood clotting: ferric chloride or alum stops bleeding from small cuts by coagulating blood.
  • Smoke precipitators in factories use electric charge to remove smoke particles.
  • River deltas form where river clay (a colloid) meets the ions of sea water.
In Sierra Leone

When fresh palm-oil soup or groundnut soup is stirred, the oil spreads through the water as tiny droplets, making an emulsion. If the soup is left to cool, the oil separates and floats to the top, because there is little emulsifier to hold it. Fog over the Freetown peninsula on cool mornings is an aerosol, and car headlights show its Tyndall effect.

Common mistake

Milk is not a true solution: it is a colloid (an emulsion of fat droplets in water). It passes through filter paper and does not settle, but it shows the Tyndall effect and looks cloudy.

Key points

  • A solution is a uniform mixture of solute in solvent; "like dissolves like".
  • Saturated = maximum solute at that temperature; supersaturated = more than that (unstable).
  • True solution: tiny particles, clear, no settling, no Tyndall effect. Colloid: intermediate particles, Tyndall effect, no settling. Suspension: large particles, settles, filterable.
  • Colloid types: sol, gel, emulsion, foam, aerosol.
  • Coagulation by oppositely charged ions (alum) is used in water treatment.

WASSCE examination focus

WAEC tests this

Expect to distinguish solutions, colloids and suspensions in a table, to describe the Tyndall effect, to classify colloids (emulsion, aerosol, sol, gel, foam) with examples, and to define saturated and supersaturated solutions. Uses of solvents in stain removal also appear.

Quick check

  1. Name the solvent you would use to remove an oil-paint stain.
  2. How would you show that a solution is saturated?
  3. Give two differences between a colloid and a suspension.
  4. What type of colloid is (a) milk, (b) smoke?

Answers:

  1. Kerosene or turpentine.
  2. Add a little more solute at the same temperature; if it does not dissolve, the solution is saturated.
  3. Any two: colloid particles are smaller; colloids do not settle, suspensions do; colloids pass through filter paper, suspensions do not; colloids are often translucent, suspensions opaque.
  4. (a) Emulsion; (b) aerosol (solid in gas).

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